I can't find the mobo you specified. Only have z77x ud3h. As far as I know for gigabyte motherboard the suffix 'x' denotes sli compatibility. For those without that suffix eg z77 ud3h, only crossfire may be supported provided there are 2 x16 physical slots available.
Crossfire and Sli have different requirement. For crossfire it is enough to have x16 and x4 electrical slots. Whereas Sli requires at least x8 in any slots eg x8 x8 or x16 x16.
Depending on resolution, generally the bandwidth on the x4 slot will drag down the other causing the maximum potential performance to be unrealized. So generally it is better to dual gpu on at least x8 slots