i will recommend nanyang optical as being the better choice. One of the oldest optical chain ard. Its Chairman, Yang Wah Kiang, has spent much of his life working with optical technology and in eyewear manufacture and design, and the Urband Origami is a demonstration of his hands-on approach to applying existing technical know-how and technology to the design of innovative eyewear. They strive to be one of the best international eyewear design and R&D companies in the world. I particularly like their in-house brands which are quite different & unique from other brands out there in the market. They are all light, comfortable, innovatively designed, value-for-money.
As for spectacles hut & optical 88, they are the "newer" optical chains. I dont see any speciality in their products. Their prices not that cheap as well. So, you may kena chopped in these places.
As for your prescription & astig high, i dont think you should get rimless frames at all, becos it will be visibly thick even if you use the highest index lenses. Furthermore, the weight of the lens will bore down on your frame at the front, so you will feel heavy on your nose & the specs will not feel so balancely-fitted. And frameless spec also has the risk of your axis running adrift, and with your high astig, even axis 1 degree off you will see blurred. Just like for me, my left eye astig is 325 degrees. So any one degree of axis off my whole vision is blurred. So i always need to remind the optician to get my axis perfectly correct while edging the lens, and hope that the lab will make it right. I will choose reputable lens brand so that to ensure better quality, eg hoya.
I strongly recommend you to choose the double aspherical design instead of the single aspherical design of your lens. Believe me, it will make a lot difference to your vision.