I get where you're coming from about grind retention! I can theoretically get all of the grinds out of mine (I already removed the finger guard from the chamber and I can see the chute and get all the grinds out.
http://coffeetimex.wdfiles.com/local--files/mazzer-mini-e-modifications/mazzermod.jpg
The thing is, if I actually do get all the grinds out, it actually disrupts the way the wire works (it slows down the flow by "accumulating" a bunch of grinds on the left hand side and freshly ground coffee comes out the right hand upside down "L"). I can remove the netting but I will lose the anti-static and clumping will occur as the grinds will stick to the chamber.
The grinds, despite coming out of the chute 90 degrees to the chamber exit actually fall down quite nicely on the centre of my basket, the main spillage is due to either overfilling or when I am distributing.
As a result I end up wasting more grounds trying to purge the old stuff (2-3g) in the chute. So you're right on that point about retention!
But if I'm not changing any settings and I'm not fussed about the grounds that are a few minutes old, I just grind as usual if I'm doing a few shots in succession as the amount/weight of the actual grind coming through is the same if you think about it (I measured it before to be sure haha).